✦ LIBER ✦

Buckminsterfullerene as a stationary phase in liquid chromatography

✍ Scribed by Kiyokatsu Jinno; Katsunori Fukuoka; John C. Fetzer; Wilton R. Biggs

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 459 KB
Volume: 5
Category: Article
ISSN: 1040-7685
DOI: 10.1002/mcs.1220050605

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Buckminsterfullerene C~60~ was used as a stationary phase for the microcolumn liquid chromatographic separation (LC) of various aromatic compounds. Carbonaceous material prepared by a general soot production process was extracted with toluene, purified using several chromatographic processes, and then packed into fused silica capillary columns for chromatographic evaluation. The performance and separation characteristics were examined. The results indicate that the C~60~ fullerene can be useful as an LC stationary phase and offers a unique shape selectivity for aromatic compounds as compared to conventional octadecylsilica phases.

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