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Brønsted Acid/Lewis Acid Cooperatively Catalyzed Addition of Diazoesters to 2 H -Chromene Acetals

✍ Scribed by Luan, Yi; Qi, Yue; Gao, Hongyi; Ma, Qianqian; Schaus, Scott E.


Book ID
126491038
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
601 KB
Volume
2014
Category
Article
ISSN
1434-193X

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## Abstract The perchlorate salt of the dicationic bipy–ruthenium complex __cis__‐[Ru(6,6′‐Cl~2~bipy)~2~(H~2~O)~2~]^2+^ effectively catalyzes addition of β‐diketones to secondary alcohols and styrenes to yield the α‐alkylated β‐diketones. In a catalytic addition reaction of acetylacetone to 1‐pheny