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Brønsted acidity of H-MCM-22 as probed by variable-temperature infrared spectroscopy of adsorbed CO and N2

✍ Scribed by Delgado, Montserrat R.; Bulánek, Roman; Chlubná, Pavla; Arean, Carlos O.


Book ID
122226251
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
597 KB
Volume
227
Category
Article
ISSN
0920-5861

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The temperature dependence of the line-shape of 1H MAS NMR spectra of H-mordenite and H-MCM-22 was examined. Upon raising the temperature of measurements stepwise from 298 to 503 K, the line-width of 1H MAS NMR of acidic protons in H-mordenite with SiO 2 /Al 2 O 3 ratio of 106 increased, went throug