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Bromohydrin formation in aqueous dimethyl sulphoxide; electronic and steric effects

โœ Scribed by Dalton, David R.; Dutta, Ved P.


Book ID
121322889
Publisher
Royal Society of Chemistry
Year
1971
Weight
574 KB
Category
Article
ISSN
0045-6470

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Native ordered structure of welan polysa
โœ Miles W.N. Hember; Robert K. Richardson; Edwin R. Morris ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 818 KB

Welan, in aqueous solution, has "weak gel" properties analogous to those of ordered xanthan but, unlike xanthan, shows no evidence of conformational change between 0 and 100 degrees C. When the polymer is dissolved in dimethyl sulphoxide (Me2SO) rather than in water, however, there is a massive decr