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Bromination/Debromination of 6-Benzoyl-3-alkyl or 3-Aryl Sydnoneimines

✍ Scribed by Beal, E. N.; Turnbull, K.


Book ID
120416178
Publisher
Taylor and Francis Group
Year
1992
Tongue
English
Weight
307 KB
Volume
22
Category
Article
ISSN
0039-7911

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1-Benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene (4a) underwent novel intermolecular 1,4-rearrangement in refluxing toluene to give an enol ether 5z while rearrangement of 2-phenyl derivative 4e proceeded intramolecularly in refluxing xylene to afford a 1,4-rearranged enol ether 5b. 5 the other hand