Bromination of Tocopherols: Oxidative Halogenations and Rearrangements
✍ Scribed by Stefan Böhmdorfer; Anjan Patel; Andreas Hofinger; Thomas Netscher; Lars Gille; Thomas Rosenau
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 435 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
Heats of formation of BrONO 2 , BrONO, BrOOH, FOOH, FOOCl, CF 3 C(O)OOH, HC(O)OOH, CH 3 C(O)OOH, and [CH 3 C(O)O] 2 are estimated from bond contributions taken from J. Phys. Chem., 100, 10150 (1996). They agree within Ϯ2 kcal/mol with recent experimental or ab initio data. The resulting kcal/mol val
## Abstract For Abstract see ChemInform Abstract in Full Text.
A new couloamperometric apparatus has been designed to extend the range of this kinetic technique to the measurement of very high rate constants, l@M-'s-', by using TFCR-EXSEL conditions (TFCR-very low reactant concentration; EXSEL-salt excess), which give half-lives of a few seconds for very fast s