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Bromination of benzhomobarrelene derivatives: 10. High temperature bromination

✍ Scribed by Abdullah Menzek; Nurullah Saraçoğlu; Arif Daştan; Metin Balci; Riza Abbasoglu

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
652 KB
Volume
53
Category
Article
ISSN
0040-4020

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Synthesis and structure elucidation of b
Synthesis and structure elucidation of bromination products from dibromohomobenzonorbornadienes: high temperature bromination—Part 17
✍ Cavit Kazaz; Arif Daştan; Metin Balcı 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract The electrophilic addition of bromine to dibromohomobenzonorbornadiene derivatives at −45 ± 5°C led to the formation of the rearranged and non‐rearranged tetrabromides in a ratio of 6:4. However, high‐temperature bromination of the same system in CCl~4~ at 77°C produced only non‐rearran