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Bromination of 1,3-dimethyl-and 1,5-dimethyl-1H-pyrazole-4-carboxylic acids

โœ Scribed by O. S. Attaryan; G. A. Akopyan; K. S. Badalyan; G. V. Asratyan


Book ID
111459172
Publisher
Springer
Year
2007
Tongue
English
Weight
104 KB
Volume
77
Category
Article
ISSN
1070-3632

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4-Hydroxymethyl-3,5-dimethyl-1H-pyrazole
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In the title compound, C 6 H 10 N 2 O, corrugated sheets parallel to the (101) plane are formed via intermolecular O-Hร ร รN and N-Hร ร รO hydrogen-bonding interactions.

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โœ Guzei, Ilia A. ;Keter, Frankline K. ;Spencer, Lara C. ;Darkwa, James ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 488 KB

In the title compound, C 24 H 22 N 2 , the bond distances and angles are typical. The central C atom exhibits a distorted tetrahedral geometry; the angles range from 106.17 (8) to 113.01 (9) . The torsion angles N-C-C(ipso)-C(ortho) involving the phenyl rings are very different, at 5.20 (14), 46.68