Bridgman-solution crystal growth and characterization of the skutterudite compounds CoSb3 and RhSb3
β Scribed by T. Caillat; J.-P. Fleurial; A. Borshchevsky
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 363 KB
- Volume
- 166
- Category
- Article
- ISSN
- 0022-0248
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The crystal structure of the chalcogenide compounds CuFeAlSe 3 and CuFeGaSe 3 , belonging to the system I-II-III-III 3 , were characterized using X-ray powder diffraction data. Both compounds crystallize in the tetragonal space group P42c (NΒΊ 112), Z = 1, with unit cell parameters a = 5.609(1) Γ , c
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Al 3 (BO 3 ) 4 (RE β«Ψβ¬ Nd, Gd, Ho, Yb, and Lu) single crystals were grown from 6uxed melts based on the potassium trimolybdate. The compounds, morphology, and structure of these crystals were studied. The average RE distribution coe7cients were found to be 0.35 to 1.02 for di4erent rare-earth elemen