✦ LIBER ✦
Bridged structures in multiply bonded silicon compounds: Disilyne, protonated disilyne and disilene
✍ Scribed by Hans-Joachim Köhler; Hans Lischka
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 826 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Ab initio SCP and electron correlation calculations are reported for the singlet ground state of the tiilc compounds. These calculations confirm earlier findings that non-planar bridged Siz H a is the most stable structure. For protonated disilyne (Si,H$) a bridged Dab structure is tbc global minimum. Two bridsed structures of Czv and C,, symmetry are found in the case of disikne (SilHqj which are only 14-17 kal/mol above the Dzh structure,