✦ LIBER ✦
Breakdown of cyclic dithiohemiorthoamide tetrahedral intermediates - RC(SR′)(NR″2)SH - at sub-zero temperatures 1,2
✍ Scribed by Moses K. Kaloustian; Liliane Khouri
- Book ID
- 104220435
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 223 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The sulfhydrolyses of thiolmidate salts 2a-2d, in the presence of Lcanh. NaSH in dry 2-butanone at -82'C, proceed by the preferential cleavage of the C-N bond rather than the C-S bond.