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Branched charge-transfer chromophores featuring a 4,5-dicyanoimidazole unit

✍ Scribed by Filip Bureš; Jiří Kulhánek; Tomáš Mikysek; Jiří Ludvík; Ján Lokaj


Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
436 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis


Six branched and stable push-pull chromophores featuring 4,5-dicyanoimidazole as an acceptor moiety, an N,N-dimethylamino group as a donor and various p-conjugated linkers are reported. Systematic extension of the p-linker revealed that the optical and electrochemical properties of A-p-D chromophores are mainly affected by the nature of the p-conjugated backbone (length and planarity) as well as by the number of appended donors.