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Branched-chain alditols. A convenient synthesis of 6-deoxy-2-O-methyl-d-mannitol and 2-C-(hydroxymethyl)-d-mannitol

✍ Scribed by Zbigniew J. Witczak; Roy L. Whistler


Book ID
107725657
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
380 KB
Volume
169
Category
Article
ISSN
0008-6215

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Synthesis of Methyl 2-O-Benzyl-6-deoxy-3
✍ Žagar, Cyrill ;Scharf, Hans-Dieter 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 534 KB

## Abstract Methyl 2‐__O__‐benzyl‐6‐deoxy‐3‐__C__‐methyl‐α‐D‐mannopyranoside (2) was synthesized in ten steps by starting from the readily available methyl 2,3‐anhydro‐4,6‐__O__‐benzylidene‐α‐D‐allo‐pyranoside (3). The key step was the stereoselective __cis__‐hydroxylation (cat. osmium(VIII) oxide)