Bowl-Shaped Tris(2,6-diphenylbenzyl)tin Hydride: A Unique Reducing Agent for Radical and Ionic Chemistry

✍ Scribed by Kouji Sasaki; Yuichiro Kondo; Keiji Maruoka

• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: English
• Weight: 184 KB
• Volume: 40
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/1521-3773(20010119)40:2<411::aid-anie411>3.0.co;2-i

✦ Synopsis

Unique selectivity, hitherto not observable in ordinary radical and ionic reactions, is achieved with the bowl-shaped tris(2,6-diphenylbenzyl)tin hydride (TDTH; see structure), which has been successfully utilized as a new reducing agent.