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Boron trifluoride promoted cleavage of benzyl carbamates

โœ Scribed by D. Subhas Bose; David E. Thurston

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
210 KB
Volume
31
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A new efficient method for the cleavage of benzyl carbamates (CBZ protective groups) is described that involves a hard acid (BFs.OE&) -soft nucleophile (EtSH) system. Unlike other available methods, this combination avoids the reduction of olefias, acetylenes, imines, halides and nitro groups, or the possibility of carboxylic ester hydrolysis.

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