✦ LIBER ✦
Boron-nitrilotriacetate, N(CH2COO)3B: Synthesis and Crystal-Structure Determinations at 293K and 110K
✍ Scribed by Edgard Müller; Hans-Beat Bürgi
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- German
- Weight
- 389 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The title compound is insoluble in aprotic solvents and decomposes in protic ones. Its crystal structure consists of discrete molecules with non‐crystallographic C^30^‐symmetry and a transannular dative BN bond (1.620(3) (Å). The molecules pack tightly (density 1.804 g cm^−2^) interacting via O…C contacts between carbonyl groups (2.92–3.05 Å)). The atoms show small vibrational motion which may be interpreted in terms of a rigid body model. Distances and angles obtained at 293 and 110 were corrected for effects of rigid body motion and do not show significant differences.