Boron derivatives of dithiophosphoric acids

✍ Scribed by Il'yas S. Nizamov; Gul'nur G. Sergeenko; Elvira S. Batyeva; Nail M. Azancheev; Vladimir A. Al'fonsov

• Book ID: 101260781
• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 134 KB
• Volume: 11
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/(sici)1098-1071(2000)11:2<102::aid-hc4>3.0.co;2-i

✦ Synopsis

The reactions of tetraphosphorus decasulfide 1 with trialkyl borates 2a,b and O-isobutyl diphenylborate 2c were studied. On the basis of these studies, a novel method of synthesizing S-boron derivatives of dithiophosphoric acids was developed. The use of low frequency ultrasonic irradiation (22 kHz, power 130 W) leads to a reduction in reaction temperature and time required for completion of the reactions studied.