In this study, new boroaluminide protective coatings were deposited on ferritic-martensitic steel substrates (P91) using the pack cementation technique, at moderate temperatures in order not to influence the substrates' mechanical properties. Extensive thermodynamic calculations were performed initially, using the Thermocalc Computer program, so as to optimize the process parameters. The most important gas-precursors for successful deposition of the coatings were identified. The effect of pack composition on the formation and growth of boroaluminides at 715 °C, using pack powders containing Al and B as element depositing sources, two halide salts as activators, and Al 2 O 3 as inert filler, was investigated. Three distinct regions were found in the coatings consisting of an outer Al-rich layer, a transition region containing Al, B and Fe and an inner layer containing mostly B, Cr and Fe. The layers were characterized by means of optical and Scanning Electron Microscopy (SEM) in terms of coating morphology and thickness. X-ray diffraction (XRD) was used in order to detect the phases formed and the presence of iron aluminide and boride phases in the coatings due to the boroaluminizing process.