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Born-Oppenheimer and hyperspherical adiabatic approximations in the nuclear- and molecular-mass limits

โœ Scribed by Sadhan K. Adhikari; V. P. Brito; H. T. Coelho; T. K. Das


Book ID
112835796
Publisher
Springer-Verlag,Italian Physical Society
Year
1992
Weight
737 KB
Volume
107
Category
Article
ISSN
0369-3554

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Molecular structure and the bornโ€”Oppenhe
โœ R.G. Woolley; B.T. Sutcliffe ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 697 KB

A discussion is attempted of the validity of the Born-Oppenheimer approximation which is characterized as an asymptotic analysis leading to a semiclassical theory of molecular structure. It is suggested that there are inherent defects in the resulting semiclassical theory which will limit its utilit