✦ LIBER ✦

Borepin and its valence isomers

✍ Scribed by Raymond L. Disch; Michael L. Sabio; Jerome M. Schulman

Book ID: 104217241
Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 194 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)81791-8

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✦ Synopsis

A_b initio calculations show borepin to be planar and more stable than its valence isomers boranorbornadiene and boranorcaradiene by a considerable amount; the latter have C, symmetry.

Borepin (I) is perhaps the most conspicuously monocyclic 4n+2 pi-electron systems. In contrast

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