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Borderline between E1cB and E2 mechanisms. Elimination of hydrogen chloride from fluorene derivatives

✍ Scribed by Thibblin, Alf.


Book ID
126398142
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
668 KB
Volume
110
Category
Article
ISSN
0002-7863

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## Abstract The mechanistic dichotomy between concerted E2 and stepwise E1cb of the base‐promoted elimination of 2‐aryl‐3‐chloro‐2‐__R__‐propanols was examined computationally at the HF, M05‐2X, and MP2 levels of theory. Optimizations of transition states (TSs) and reaction intermediates, and intri