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Borate Glasses: Structure, Properties, Applications

✍ Scribed by N. J. Kreidl (auth.), L. D. Pye, V. D. Fréchette, N. J. Kreidl (eds.)


Publisher
Springer US
Year
1978
Tongue
English
Leaves
630
Series
Materials Science Research 12
Edition
1
Category
Library

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✦ Synopsis


Boron Oxide plays a key role in numerous glasses of high technological importance, yet its role in glass structure is far from clear. Indeed, in recent years there have been serious chalΒ­ lenges to previous structure concepts for both crystalline and glassy borates. These challenges were sufficient to warrant a reΒ­ examination of the structure of borate glasses using the most powΒ­ erful tools currently available. To provide a suitable forum for this undertaking, a four-day conference on "Boron in Glass and Glass Ceramics" was convened at Alfred University, June 3-8, 1977 to review the best scientific thinking on structure and to debate conflicting views and discuss properties and applications of borate glasses. This conference was also the first in a New University series on Glass Science to be rotated among Alfred University, The Pensyl vania State University, Rensselaer Polytechnic Institute, and the University of Missouri-Rolla. The present volume represents the proceedings of the first conference in this series. The volume begins with a review of the remarkable contribution of Jan Krogh-Moe to the understanding of the structure of Borate glasses. This review, authored by Professor N. J. Kreidl, concludes by dedicating the proceedings of this conference as a Krogh-Moe FestΒ­ schrift. The volume continues with a historical review by D. L. Griscom, originally prepared for circulation to the contributors prior to the conference. An Epilogue to the opening chapter brings the survey up-to-date in light of the conference papers.

✦ Table of Contents


Front Matter....Pages i-x
A Dedication to Krogh-Moe: His Contribution to the Understanding of Borate Glasses....Pages 1-10
Borate Glass Structure....Pages 11-138
Epilogue....Pages 139-149
Quantum Chemical Calculations to Model Borate Glass Electronic Structure and Properties....Pages 151-165
Topological Considerations of Triangularly Connected Networks....Pages 167-181
On the Fluctuation Structure of Vitreous Boron Oxide and Two-Component Alkali Borate Glasses....Pages 183-199
Diffraction Analysis of Vitreous and Molten B 2 O 3 ....Pages 201-213
Laser-Induced Fluorescence Line Narrowing of Eu 3+ in Lithium Borate Glass....Pages 215-226
MΓΆssbauer Investigation of the Incorporation of Tin and Iron in Sodium Borate Glasses....Pages 227-238
Induced Silver Centers in Alkali Borate Glasses....Pages 239-257
Structure of Borate and Borosilicate Glasses by Raman Spectroscopy....Pages 259-279
Structure of Borate Glasses by Raman Spectroscopy....Pages 281-296
Infrared Spectra and Structure of CVD B 2 O 3 -SiO 2 Glasses....Pages 297-306
The Vibrational Analysis of Boron in Vitreous Silica....Pages 307-319
NMR Studies of Borates....Pages 321-351
Structural Determinations for Sodium Borate Glasses Using B 10 and B 11 NMR....Pages 353-367
Random Vector Statistical Studies of Amorphous Materials....Pages 369-376
A Gas Probe Analysis of Structural Trends in Boron Glasses....Pages 377-385
High-Temperature Borate Liquids: Physical Properties of Glass-Forming Compositions....Pages 387-398
Kinetics of Volatilization of Sodium Borate Melts....Pages 399-411
Viscous Flow in Binary Borate Melts....Pages 413-426
Immiscibility and Microstructure in Amorphous Borates....Pages 427-443
Crystal Growth Kinetics in Binary Borate Melts....Pages 445-462
Viscoelastic Relaxation in B 2 O 3 ....Pages 463-476
Glass Formation in Borate Systems....Pages 477-490
Electrical and Dielectric Properties of Borate Glasses....Pages 491-508
Chemical Stability of Boron Containing Glass Enamels with Special Reference to Lead Release....Pages 509-523
Chemical Durability of Borate Glasses....Pages 525-537
Properties of Silica Glasses Containing Small Amounts of B 2 O 3 ....Pages 539-548
Optical Properties of the Sodium-Borate Glass System....Pages 549-566
Effect of Water Content on Density, Refractive Index, and Transformation Temperature of Alkali Borate Glasses....Pages 567-575
Acoustic Spectra of Glasses in the System Na 2 O-B 2 O 3 ....Pages 577-585
Industrial Borate Glasses....Pages 587-596
Application of Borate Glasses and Various Boron Bearing Glasses to the Management of French Radioactive Wastes....Pages 597-616
Application of Borate Glasses in Electronics....Pages 617-622
Reaction Cured Borosilicate Glass Coating for Low-Density Fibrous Silica Insulation....Pages 623-634
Back Matter....Pages 635-637

✦ Subjects


Ceramics, Glass, Composites, Natural Methods


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