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Borate ester-induced decomposition of alkyl hydroperoxides. The epoxidation of olefins by electrophilic oxygen

✍ Scribed by Wolf, Philip F.; Barnes, Robert K.


Book ID
121393203
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
660 KB
Volume
34
Category
Article
ISSN
0022-3263

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In the ferrous ion induced decomposition of alkyl hydroperoxides in the presence of cupric halides or pseudohalides, intramolecular functionalization, with ligand transfer from cupric salts to S-carbon atom, is achieved. Alkoxy radicals containing more than four carbon atoms in an alkyl chain, gener