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Boranes. XXXVII. Reactions of triborane(7) and the structure of triborane(7) carbonyl

โœ Scribed by Glore, James D.; Rathke, Jerome W.; Schaeffer, Riley

Book ID
127241885
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
536 KB
Volume
12
Category
Article
ISSN
0020-1669

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The electronic structures of bis(carbony
The electronic structures of bis(carbonyl)diborane(4), triborane(7) carbonyl and their parent boranes diborane(4) and triborane(7)
โœ D.R. Armstrong ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 603 KB

The electronic structure of bLs(carbonyl)diborane(4), B,H,(CO),, triborane(7) carbonyl, B3H,C0, and their parent boranes have been examined by a non-empirical molecular orbital technique. It is found that the carbonyl groups are weakly bound to the borane portion. The staggered form of B2H4(C0)2 is