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Boosting the Nucleophilicity of Phosphole Lone Pairs by Isomerization †

✍ Scribed by Ciric, Ana; Mathey, François

Book ID
126593726
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
988 KB
Volume
29
Category
Article
ISSN
0276-7333

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📜 SIMILAR VOLUMES

The important role of the phosphorus lon
The important role of the phosphorus lone pair in phosphole aromaticity
✍ D. B. Chesnut; L. D. Quin 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

## Abstract Calculations on phosphole systems using the G3MP2B3 model chemistry show that the phosphorus lone pair is critical to the system's aromaticity. Protonation of the lone pair results in antiaromatic molecules as measured by homomolecular homodesmotic reactions. Attempts to separate out ef