Book Review: Polarography of Molecules of Biological Significance. Edited by W. F. Smyth

✍ Scribed by Gerhard Eisenbrand

• Publisher: John Wiley and Sons
• Year: 1980
• Tongue: English
• Weight: 134 KB
• Volume: 19
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198004091

✦ Synopsis

the quality of the lamp. The reaction mixture was monitored semi-continuously by gas-phase IR (sampling every 2-5 min). The products were purified by fractional condensation. Besides the given products, SF, is also formed

(3): IR: 1315 (s), 1237 (s), 1162 (s), 1066 (m), 895 (m), 847 (s), 836 (s), 742 (m), 605 cm-' (w); EI-MS: m/e=222 (16%) 1222 (s), 1187 (m), 1139 (w), 1096 (s), 1066 (w), 1029 (w), 941 (w), 907 (m), 853 (w), 825 (w), 783 (vw), 755 (vw), 714 (w), 695 (m), 660 (s), 629 (vw), 613 cm-' (vw); EI-MS: m/e=393 (2%) (M-F)+.-The data for (4)"l and (5)[1.41 are in complete agreement with those given in the literature.

Irradiation of (5) (6.0 g) in the presence of an excess of fluorine affords, within 48 h, 2.5 g of ( ) (36% yield) besides 2.0 g of (4) (40% yield).