𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bonding Trends in Lewis Acid Adducts of S4N4 — X-Ray Structure of TeCl4×S4N4.

✍ Scribed by Jari Konu; Tom Bajorek; Risto S. Laitinen; Tristram Chivers; Reijo J. Suontamo; Markku Ahlgren

Publisher
John Wiley and Sons
Year
2006
Weight
9 KB
Volume
37
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Bonding Trends in Lewis Acid Adducts of
Bonding Trends in Lewis Acid Adducts of S4N4 – X-ray Structure of TeCl4·S4N4
✍ Jari Konu; Tom Bajorek; Risto S. Laitinen; Tristram Chivers; Reijo J. Suontamo; 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 231 KB

## Abstract Tetrasulfur tetranitride and tellurium tetrachloride react in dichloromethane to form a 1:1 adduct TeCl~4~·S~4~N~4~ (1). The crystal structure of 1 shows that TeCl~4~ is bonded to the S~4~N~4~ ring through a Te–N linkage. As a consequence, the transannular S···S bonds in S~4~N~4~ are br

Relativistic pseudopotential calculation
Relativistic pseudopotential calculation of bonding trends in XAum+n clusters (X = B−N, Al−S; n = 4−6)
✍ Pekka Pyykkö; Yongfang Zhao 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 290 KB

I 1 -electron quasirelativistic pseudopotential of Hay and Wadt. The results are lo-22 pm larger than the five experimentally known values for X(AuPPh,);+ systems. For second-row central atoms, R increases with n, in agreement with experiment. For third-row central atoms, the curves cross. The X-Au