✦ LIBER ✦
Bonding properties of group VIB metal pentacarbonyl azole complexes studied by electronic absorption, photoelectron, 13C NMR and vibrational spectroscopy
✍ Scribed by H. Daamen; A. Oskam; D.J. Stufkens; H.W. Waaijers
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 693 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
✦ Synopsis
The electronic absorption, photoelectron, 13C NMR and vibrational spectra of a series of M(CO),L complexes (M = 0, W and L = imidazole, pyrazole, isoxazole, thiazole and isothiazole) are reported and assigned. The results are used to interpret the o and n-bonding between the metal and the nitrogen donor ligand. The metal-azole bond. is compared with the metal-pyridine and -pyrazine bond in the corresponding complexes.