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Bonding in phosphorus oxyfluoride and phosphorus thiofluoride. An ab initio SCF LCAO MO study

✍ Scribed by A. Serafini; J.-F. Labarre

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 240 KB
Volume: 27
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)90257-7

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✦ Synopsis

A comparison

of the electronic structures of the molecules OPFs and SPFs is performed within the framework of an ab initio SCF LCAO MO study. In complete agreement with the empirical assumptions provided by previous magneto-optical experiments, the (P-S) bond in SPFs is weaker, endowed with a higher n character and less polar than the (P-O) bond in OPF3

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