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Bond length and radii variations in fluoride and oxide molecules and crystals

✍ Scribed by J. S. Nicoll; G. V. Gibbs; M. B. Boisen; R. T. Downs; K. L. Bartelmehs

Publisher
Springer-Verlag
Year
1994
Tongue
English
Weight
926 KB
Volume
20
Category
Article
ISSN
0342-1791

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πŸ“œ SIMILAR VOLUMES

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Bond lengths calculated for the coordination polyhedra in hydronitride molecules match average values observed for XN bonds involving main group X-cations in nitride crystals to within ~ 0.04 ~. As suggested for oxide and sulfide molecules and crystals, the forces that determine the average bond len

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## Abstract A series of saturated __X__~__n__~H~__m__~ (__X__ being either C or Si) molecules is studied using the MINDO/3 and MNDO quantum‐chemistry procedures. We find that the proximity of H atoms tends to shorten __X__ο£Ώ__X__ bonds, and that this effect is (especially for MINDO/3) much larger th