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Bond-forming reactions to an iridium-coordinated hydroxo group: reaction of trans-Ir(CO)(OH)[P(p-tolyl)3]2 with MeI, EtI, HCl, CH3COCl, and H2

โœ Scribed by Thompson, Jeffrey S.; Randall, Sherri L.; Atwood, Jim D.

Book ID
126177405
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
666 KB
Volume
10
Category
Article
ISSN
0276-7333

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Formation of a heterobimetallic compound
Formation of a heterobimetallic compound by reductive elimination of methane and oxidative cleavage of an aryl-phosphorus bond in reaction of trans-MeIr(CO)[P(p-tolyl)3]2 with HMoCp(CO)3: Crystal and molecular structures of CpMo(CO)2[.mu.-P(p-tolyl)2]Ir(p-tolyl)[P(p-tolyl)3](CO)2 (Mo-Ir) and CpMo(CO)2[.mu.-P(p-tolyl)2]Ir(H)[P(p-tolyl)3](CO)2 (Mo-Ir)
โœ McFarland, Jeffrey M.; Churchill, Melvyn Rowen.; See, Ronald F.; Lake, Charles H ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 1001 KB