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Bond-Forming Reactions of Dications with Molecules: A Computational and Experimental Study of the Mechanisms for the Formation of HCF 2+ from CF 32+ and H 2†

✍ Scribed by Lambert, Natalie; Kaltsoyannis, Nikolas; Price, Stephen D.; Žabka, Jan; Herman, Zdenek


Book ID
126330862
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
159 KB
Volume
110
Category
Article
ISSN
1089-5639

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An alternative mechanism of BH2SH format
✍ Alexander M. Mebel; Djamaladdin G. Musaev; Keiji Morokuma 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 411 KB

An alternative mechanism of mercaptoborane, BH,SH, formation is proposed for the reaction of BzHs with SH2. It involves concerted elimination of BH3 and H2 from the H2SB2Hs complex and the highest energy on the pathway relative to SH, + B2H6 is 27.4 kcal/mol at MP4(SDTQ)/6-31 +G(2d, p)//MP2(FULL)/6\