The modified electron gas ionic model predicts bond distances in a series of 16 gaseous metal halides without occupied d orbitals with an average error of 5 picometer (pm), but for d n compounds calculated distances exceed experimental by 30 pm. Errors in calculated cohesive energies correlate stron
Bond Energies and Ionic Character of Inert Gas Halides
โ Scribed by Waters, James H.; Gray, Harry B.
- Book ID
- 127341643
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 300 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Extended basis set calculations yield a dissociation energy AhE(MeLi --, Me + Li) = 46.4 f 1.2 kcal mol -'. The Me-Li bond has non-negligible covalent contributions. Comparison with the series of molecules NaF, NaCI, LiF and LiCl shows that the covalent contribution in MeLi is more pronounced than i
## Abstract **A reliable descriptor** of the bond strength is the stretching force constant associated with the adiabatic vibrational mode that is localized in the bond and does not couple with other vibrational modes. This is used for a comparison of C๏ฃพF^+^ and C๏ฃพO bonds (see picture).magnified im