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Bond distance inversion in the equilibrium geometry of the coupled tricyclo[3.1.0.02,6]hexyl molecule C12H14. A puzzling problem in molecular structure

✍ Scribed by Yaoming Xie; Henry F. Schaefer III


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
265 KB
Volume
168
Category
Article
ISSN
0009-2614

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✦ Synopsis


The equilibrium geometry of the title compound has been completely optimized via ab initio quantum mechanical methods using basis sets as large as double-zeta plus polarization (DZ t P) functions, i.e. C( 9~5~1 d/4s2pl d), H (4slp/2slp). As hypothe-