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Blue-Emitting Platinum(II) Complexes Bearing both Pyridylpyrazolate Chelate and Bridging Pyrazolate Ligands: Synthesis, Structures, and Photophysical Properties

✍ Scribed by Chang, Sheng-Yuan; Chen, Jing-Lin; Chi, Yun; Cheng, Yi-Ming; Lee, Gene-Hsiang; Jiang, Chang-Ming; Chou, Pi-Tai

Book ID: 127270799
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 464 KB
Volume: 46
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic701586c

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~