Block copolymers of poly(vinyl ethers) and poly(ethylene glycol) by means of the living cationic polymerization of vinyl ethers
✍ Scribed by Ton Loontjens; Frank Derks; Engelien Kleuskens
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 283 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0170-0839
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📜 SIMILAR VOLUMES
## Abstract The living cationic random copolymerization of MVE and CEVE to obtain functionalized thermo‐responsive PMVE as precursors for more complex PMVE‐containing polymer structures is reported. The random copolymers P(MVE‐__co__‐CEVE) were synthesized at 0 °C in toluene using the DEE/TMSI/ZnI~
## Abstract Hydroxy‐terminated telechelic poly(2‐chloroethyl vinyl ether) (poly(CEVE)) was synthesized by water‐based end‐capping reaction of living poly(CEVE) with the initiating system CH~3~CHClOCH~2~CH~2~OCOCH~3~/ZnCl~2~ in CH~2~Cl~2~ at −40°C and subsequent end‐group transformation of the ace