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Block copolymers of N-vinyl carbazole and α,ω-dihydroxy polydimethylsiloxane

✍ Scribed by Ahmet Akar; Nilgun Kizilcan; Belkis Ustamehmetoglu; Demet Colak; A. Sezai Sarac; Cengiz Colak


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
368 KB
Volume
106
Category
Article
ISSN
0021-8995

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Abstraet--Carbazole units in copolymers can be cross-linked by reaction with a Lewis acid catalyst in methylene chloride. The reaction initially causes gel formation, followed by the development (with BF3. Et20) of a characteristic blue colour. The blue product has been shown to be a cationic dye of

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Steady-state and time-resolved fluorescence techniques have been used to study the photophysical behaviors of poly(N-vinyl carbazole), PNVCz and a series of N-vinyl carbazole-methyl acrylate (NVCz-co-MA) copolymers in dilute solution as a function of both NVCz composition and temperature. A kinetic