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Blends of aliphatic polyesters. VIII. Effects of poly(L-lactide-co-ε-caprolactone) on enzymatic hydrolysis of poly(L-lactide), poly(ε-caprolactone), and their blend films

✍ Scribed by Hideto Tsuji; Tamami Yamada


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
339 KB
Volume
87
Category
Article
ISSN
0021-8995

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Phase-separated blend films were prepared with the solution casting method from poly(L-lactide) (PLLA) and poly(-caprolactone) (PCL) with different PLLA contents [X PLLA (w/w) ϭ PLLA/(PCL ϩ PLLA)] and their biodegradation was investigated in soil up to 20 months by gravimetry, gel permeation chromat

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## Abstract Fourier transform infrared (FTIR) spectroscopy was used to reveal intermolecular interactions between carbon dioxide (CO~2~) and the carbonyl groups of poly(L‐lactide) (PLLA), poly(D,L‐lactide) (PDLLA), and poly(ε‐caprolactone) (PCL). After exposing polymer films to high pressure CO~2~,