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Blending of HAuCl4 and histidine in aqueous solution: a simple approach to the Au10 cluster

✍ Scribed by Yang, Xi; Shi, Minmin; Zhou, Renjia; Chen, Xiaoqiang; Chen, Hongzheng


Book ID
120009788
Publisher
The Royal Society of Chemistry
Year
2011
Tongue
English
Weight
377 KB
Volume
3
Category
Article
ISSN
2040-3364

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Full geometry optimixations have been carried out on molecular models of [M(H20)6]n+, [M(H20)~..H20]"+ and [M(H,O),...Cl] ("-'r\* (M=K and MB, n= 1 for K and 2 for Mg) using the density functional methods. The optimized geometries of [K(H20)6]+ and [Mg(HzO)s]2+ were a regular octahedron. In the opti