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Bleach and oxidation catalysis by manganese–1,4,7-triazacylononane complexes and hydrogen peroxide

✍ Scribed by Ronald Hage; Achim Lienke


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
334 KB
Volume
251
Category
Article
ISSN
1381-1169

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📜 SIMILAR VOLUMES


Efficient stereoselective oxygenation of
✍ John R. Lindsay Smith; Georgiy B. Shul'pin 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 233 KB

The dinuclear manganese complex [LMnrV(O)3MnVeL](PF6)2, where L is 1,4,7-trimethyl-l,4,7-triazacyclononane, catalyses the oxygenation ofalkanes by peroxyacetic acid or by H202 in the presence of acetic acid to give alkanols, alkanones and alkyl hydroperoxides. The reactions can give large turnovers