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Bivalent, Trivalent, and Tetravalent Nickel Complexes with a Common Tridentate Deprotonated Pyridine Bis-Amide Ligand. Molecular Structures of Nickel(II) and Nickel(IV) and Redox Activity

✍ Scribed by Patra, Apurba Kumar; Mukherjee, Rabindranath


Book ID
124058435
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
175 KB
Volume
38
Category
Article
ISSN
0020-1669

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Structure and Highly Stereoselective For
✍ Klaus Bernauer; FranΓ§ois Gretillat; Helen Stoeckli-Evans; Ruth Warmuth πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 German βš– 618 KB

The X-Ray structures of the 1:l copper(I1) complexes with racemic and optically active (+)-(R,R)-(2,6bis(pyrro1idin-2-y1)pyridine ((+)-bpp; (+)-I) were determined. Whereas the perchlorate 1 of the racemic complex contains the monomeric units with perfect C, symmetry, the sulfate of the optically act