✦ LIBER ✦
Bis(μ-1-acetimido-4-phenylpyrazolone-N2:O)-μ-oxo-tetraoxodimolybdenum(VI) as its diacetonitrile adduct: a novel dinuclear molybdenum complex bridged by a 1-acetimido-4-phenylpyrazolone ligand
✍ Scribed by Guo, Sheng-Li ;Wagner, Matthias ;Bolte, Michael
- Book ID
- 104478795
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 290 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Mo 2 O 5 (C 11 H 10 N 3 O) 2 ]Á2CH 3 CN, is a dinuclear molybdenum complex. It has crystallographic C 2 symmetry with the central O atom located on a twofold rotation axis. The Mo atoms, octahedrally coordinated by four O and two N atoms, are bridged by a "-O and two "pyrazolonyl groups. An intermolecular NÐHÁ Á ÁO hydrogen bond stabilizes the crystal packing.