𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis(tri- tert -butylsilyl)silylene: Triplet Ground State Silylene

✍ Scribed by Sekiguchi, Akira; Tanaka, Takashi; Ichinohe, Masaaki; Akiyama, Kimio; Tero-Kubota, Shozo

Book ID
120559401
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
98 KB
Volume
125
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Computational prediction of a ground-sta
Computational prediction of a ground-state triplet arylnitrenium ion and a possible ground-state triplet silylene
✍ Christopher J. Cramer; Daniel E. Falvey πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 295 KB

Density functional calculations predict that bis- (2,6-di4-butyl)phenylnitrenium has a triplet gmund stal~ and that the corresponding silylene has essentially degenerate singlet and triplet states. The steric bulk of the aryl ligand strongly destabilizes the singlets in each case relative to the tri