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Bistability transition in the self-trapping of an electron in a one-dimensional molecular chain

โœ Scribed by Phuoc X. Tran

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
429 KB
Volume
123
Category
Article
ISSN
0375-9601

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Synthesis of the One-dimensional Compound (Ph4P)[In(P2Se6)] in a Ph4P+-Containing Selenophosphate Flux, and Structure of [In(P2Se6)2]5โ€“ โ€“ a Discrete Molecular Fragment of the [In(P2Se6)]nnโ€“ Chain
โœ Konstantinos Chondroudis; Debojit Chakrabarty; Enos A. Axtell; Mercouri G. Kanat ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 137 KB ๐Ÿ‘ 2 views

The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 ยฐC gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 ยฐC produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst