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Bis(phosphinimino)methanides as Ligands in Divalent Lanthanide and Alkaline Earth Chemistry — Synthesis, Structure, and Catalysis.

✍ Scribed by Tarun K. Panda; Agustino Zulys; Michael T. Gamer; Peter W. Roesky


Publisher
John Wiley and Sons
Year
2006
Weight
17 KB
Volume
37
Category
Article
ISSN
0931-7597

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Bis(phosphinimino)methanide Rare Earth A
✍ Marcus Rastätter; Agustino Zulys; Peter W. Roesky 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 309 KB 👁 1 views

## Abstract A series of yttrium and lanthanide amido complexes [Ln{N(SiHMe~2~)~2~}~2~{CH(PPh~2~NSiMe~3~)~2~}] (Ln=Y, La, Sm, Ho, Lu) were synthesized by three different pathways. The title compounds can be obtained either from [Ln{N(SiHMe~2~)~2~}~3~(thf)~2~] and [CH~2~(PPh~2~NSiMe~3~)~2~] or from K