Palladium arenethiolates with intramolec
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Maurits D. Janssen; David M. Grove; Gerard van Koten; Anthony L. Spek
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Article
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2010
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Elsevier Science
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English
β 689 KB
## Abstract The reaction of [PdCl~2~(MeCN)~2~] with one or two equivalents of Me~3~SiSC~6~H~4~NMe~2~β2 in toluene affords the mono(arenethiolate) complex [PdCl(SC~6~H~4~NMe~2~β2)] (1) or the bis(arenethiolate) complex [Pd(SC~6~H~4~NMe~2~β2)~2~] (2), respectively, in high yields. [PdCl(SC~6~H~4~NMe~