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Bisphenolate iron(II) complexes with intramolecularly coordinating nitrogen Lewis bases

✍ Scribed by Jim A.M Brandts; Maurits D Janssen; Marinus P Hogerheide; Jaap Boersma; Anthony L Spek; Gerard van Koten


Book ID
108331805
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
161 KB
Volume
291
Category
Article
ISSN
0020-1693

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Palladium arenethiolates with intramolec
✍ Maurits D. Janssen; David M. Grove; Gerard van Koten; Anthony L. Spek πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 689 KB

## Abstract The reaction of [PdCl~2~(MeCN)~2~] with one or two equivalents of Me~3~SiSC~6~H~4~NMe~2~‐2 in toluene affords the mono(arenethiolate) complex [PdCl(SC~6~H~4~NMe~2~‐2)] (1) or the bis(arenethiolate) complex [Pd(SC~6~H~4~NMe~2~‐2)~2~] (2), respectively, in high yields. [PdCl(SC~6~H~4~NMe~