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Bis(oxazoline)×Copper(I)-Catalyzed Enantioselective Cyclopropanation of Cinnamate Esters with Diazomethane.

✍ Scribed by Andre B. Charette; Marc K. Janes; Helene Lebel


Publisher
John Wiley and Sons
Year
2003
Weight
150 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract A thorough experimental and theoretical study of the enantioselective cyclopropanation of alkenes catalyzed by chiral bis(oxazoline)– and azabis(oxazoline)–copper complexes, which comprise a new family of ligands that lack __C__~2~ symmetry, has been conducted. Surprisingly high enantio