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Bismuth(III) Chloride Catalyzed Cycloisomerization of Enynes

✍ Scribed by Zezhou Wang; Shiyue Fang


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
141 KB
Volume
2009
Category
Article
ISSN
1434-193X

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Bismuth-catalyzed cyclization of amino-1
✍ Kimihiro Komeyama; Motoyoshi Miyagi; Ken Takaki πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 149 KB

## Abstract Bi(OTf)~3~ effectively catalyzed the cyclization of amino‐1,6‐enynes, leading to bicyclic amine and cyclopentadienyl amino compounds. The selectivity of the products depends on the substitution pattern of the olefinic moiety. ^19^F NMR trace experiment of the reaction and other results