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Bismuth(III) Bis(trifluoromethanesulfonyl)amide.

✍ Scribed by Alexandre Picot; Sigrid Repichet; Christophe Le Roux; Jacques Dubac; Nicolas Roques


Publisher
John Wiley and Sons
Year
2003
Weight
94 KB
Volume
34
Category
Article
ISSN
0931-7597

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The loosely associated centrosymmetric structure of [Bi(S 2 CNC 4 H 8 ) 2 (NO 3 )] 2 features chelating dithiocarbamate and nitrate ligands, as well as weak intermolecular Bi-S interactions, so that a distorted pentagonal bipyramidal S 5 O 2 coordination geometry results.