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Bismuth valence order-disorder study in BaBiO3 by powder neutron diffraction

✍ Scribed by C. Chaillout; A. Santoro; J.P. Remeika; A.S. Cooper; G.P. Espinosa; M. Marezio


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
536 KB
Volume
65
Category
Article
ISSN
0038-1098

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In the potassium-rich part of the binary system Na 4 B 8 O 14 -K 4 B 8 O 14 solid solutions have been found that can be described with the formula (Na 1-x K x ) 4 B 8 O 14 with 0.45 ≀ x < 1.0. The crystal structures of (Na 0.25 K 0.75 ) 4 B 8 O 14 and (Na 0.45 K 0.55 ) 4 B 8 O 14 were refined at roo